You'll have trouble finding a buck/boost PCB that will output enough amps to charge them quickly. If you want a high charge rate you need to look at radio control chargers, such as used for cars, planes, quads. They provide the protection circuitry needed when charging (the risky part with lithiums) and can also provide the amps required for charging high capacity cells in a timely manner. Charge a 10000Mah pack to ~85% in 15 minutes rather than ~6 hours or more. RC'ers are not going to wait around all day for a pack to charge, when the one they're running is low the second pack on the charger needs to be ready to go so they can swap them out. You can get RC chargers up to 1200W output or more.
You can not charge a Li-Ion/Li-Poly cell while it's under load (in use). It has to be disconnected from the load to charge it due to the strict voltage limitations for lithium cells. Attempting to do so you may experience a "vent with flame" event, and it's not pretty. The smoke is very toxic and corrosive to any metal it contacts, plus it will set fire to anything around it.
I pulled these two out of my refrigerated storage to make up a pack for my RPi with the 7" display. I buy them when on sale, charge to ~3.80V storage voltage if they're not there already, and stick them in the garage fridge. They'll keep nicely there for years until I need them.
These are 40C rated cells (200A burst) and have a manufacturers claimed 5C charge rate, though I will only use 4C as a max. I can charge these at 20A (40A with two in parallel) up to about 85% when it has to switch to constant voltage charge. Then it's just a matter of how long I want to leave them on there. The undeniable fact is that it takes at least an hour and a half to fully charge a cell to 4.2V no matter what you do. Since the charger can never exceed 4.2V when the cells get to 4.1V there is only a tenth of a volt potential difference, so charge current drops way off. That's why many RC'ers, and the supposed "quick lithium chargers" for phones/tablets only do a partial charge rather than top if off all the way.
So I'll charge these with an RC charger, probably about 20 minutes or so, then I'll have enough to run the RPi with display for about 6~7 hours, maybe a little more. Then another 20 minutes to juice it back up and go again.

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