From the config.txt documentation
here. The only settings specifically for the composite output are
sdtv_mode to change between NTSC and PAL
sdtv_aspect to change the aspect ratio to one of 4:3, 14:9 or 16:9
sdtv_disable_colourburst Setting this to 1 disables colour burst on composite video output. The picture will be displayed in monochrome, but it may possibly be sharper.
Composite video is poor compared to good HDMI displays.