Your setup is what I tried to achieve myself, but there were some drawbacks to the MP2636 that prevent it.
There is a pin on the IC which, when shorted to 0v will halt the boost module and put it in an ultra low power state (effectively off). Unfortunately, this pin is not accessible, so you need to disconnect the battery whenever the Pi is intended to be fully off.
The switch between the boost module and the Pi is not strictly necessary, I use it as a "master switch", you could always use the dt shutdown overlay and a push button to turn the Pi on and off - if using a switch like I have, always power the Pi off via a proper shutdown.
The MP2636 is not the best best choice for recharging while powered.
While it can do it, I found that some modules caused the Pi to reset upon insertion or removal of the charging cable that was later determined to be caused by inrush current.
You'll also need to either change the charging current by replacing an SMD resistor, or use a ~5A power supply so the Pi can still use 2.5A while the battery charges at the default 2.5A