I do not think any spectral sensitivity graphs have been published for the Pi NoIR device. I think it would be very helpful if someone did! I can publish an image looking into a spectroscope, but only if someone gives me a camera

All the US suppliers are currently sold out.
In general, for a CMOS imager, a 850 nm illuminator will show up more brightly than 940 nm where silicon imager sensitivity is dropping off. However Adafruit is suggesting their 940 nm IR LEDs alongside the Pi-NoIR camera:
http://www.adafruit.com/products/1567#Technical_Details so presumably, 940 nm works at least to some extent.
Just for reference, with the IR filter in place, you don't see much image below about 680 nm. Here is the original R-Pi camera (including its stock IR filter) looking into spectroscope, with compact-fluorescent light:
Original R-Pi camera, spectroscope, with tungsten-filament lamp:
Original R-Pi camera looking at near-IR LED on Sony Digital8 camera (I did not measure the wavelength)
What that IR illuminator on the above Sony Digital8 camera looks like, using a different IR-sensitive CCD camera:
