Thinking about it further, I can't be certain if I inserted a space between Raspberry and Pi.

Very interesting comments.
The exact label format I used was, "Raspberry Pi", without the quotes.
After several attempts to go beyond the boot stage, I simply deleted the label and left it empty.
I'm not clever enough to explain how that alteration changed things.

More info. regarding my problem with the unseen free memory on the SD card.

When I first formatted the SD card, I set a volume label for the SD card called, "RaspberryPi".

Once I removed that, everything workd fine.

Maybe it interfered with the boot-up routine?

Sorry, but what is df -h?

Did not format it with size adjustment. Yet I tried again with size adjustment and it still shows zero memory available.

I formatted it through windows with the SD Formatter prog.
Windows recognised the full 32 GB

I have bought a 32GB micro Sd card and I formatted and loaded NOOBS onto it through Windows.
However, the Raspberry Pi does not appear to recognise the 32 GB SD card and shows that I have no memory left. Meaning, that I cannot install other programs.
Can anyone help please?